Title

Polymeric Sulfur-, Phosphorus-, Carbon - Nitrogen - Compounds

Date

1965

Index Abstract

Not Available

Photo Quality

Not Needed

Report Number

AFML TR 64-368

Creator

Appel, R.

Eisenhauer, G.

Gerber, H.

Corporate Author

Universitat Heidelberg

Laboratory

Air Force Materials Laboratory

Extent

55

Identifier

AD0629761

Access Rights

Distribution of this document is unlimited.

Distribution Classification

1

Contract

AF 61(052)-361

DoD Project

7342

DoD Task

734201

DTIC Record Exists

Yes

Distribution Change Authority Correspondence

None

Distribution Conflict

No

Abstract

The following bi-functional compounds were synthesized as starting materials for the synthesis of inorganic polymers with sulphur-nitrogen-carbon bonds: Sulfuryl-diisocyanate, O2S(NCO)2; amidosulfuric acidisocyanate, H2NSO2NCO; chlorosulfuryl-isocyanate, C1SO2NCO; fluorosulfuryl-isocyanate, FSO2NCO; imido-bis-sulfuric acid chloride, HN(SO2C1)2, and imido-bis-sulfuric acid fluoride, HN(SO2F02. The polyaddition of diamines and diols with O2S(NCO)2 results in polymers which are not very stable to temperature and hydrolysis. The polymers found by reaction of H2NSO2NCO with urea and sulfamide, O2S(NH2)2, likewise, are not very stable. In the field of the phosphorus-nitrogen- compounds the synthesis of triphenylphosphine-imines and of N-halogen-phosphine imines is described. Further experiments deal with antimony-nitrogen compounds and their reactions.

Report Availability

Full text available by request

Date Issued

1965-12

Provenance

Bearcat

Type

report

Format

55 pages ; 28 cm.