Advanced Oxidizer Chemistry

Item

Title
Advanced Oxidizer Chemistry
Report Number
AFOSR 67-2645
Creator
Solomon, Irvine J.
Corporate Author
IIT Research Institute
Laboratory
Air Force Office of Scientific Research
Corporate Report Number
Report No. IITRI-C227-20
Date
1967
Date Issued
1967-09-11
Extent
32
Contract
AF 49 (638)-1175
NTRL Accession Number
AD661583
Identifier
AD0661583
Abstract
Work on the structure of dioxygenyl fluoroborate is nearing completion. Raman spectral data, and F18 tracer studies, are consistant with the O2 Structure. Decomposition kinetics point to an OOF intermediate in the decomposition of O2BF4. It was also found that dioxygenyl fluoborate can be prepared by two new and interesting photochemical reactions the reaction of oxygen, fluorine and boron trifluoride and the reaction of oxygen difluoride and boron trifluoride. Tracer techniques have shown that the reaction of O2F2 with SO2 proceeds via an OOF intermediate. This work is now complete and all the O17 NMR data is presented. The OOF group was also transferred to carbon in that at least two OOF compounds are prepared by the reaction of either O2F2 or O4F2 with perfluoropropylene.
Description
Work on the structure of dioxygenyl fluoroborate is nearing completion. Raman spectral data, and F18 tracer studies, are consistant with the O2 Structure. Decomposition kinetics point to an OOF intermediate in the decomposition of O2BF4. It was also found that dioxygenyl fluoborate can be prepared by two new and interesting photochemical reactions the reaction of oxygen, fluorine and boron trifluoride and the reaction of oxygen difluoride and boron trifluoride. Tracer techniques have shown that the reaction of O2F2 with SO2 proceeds via an OOF intermediate. This work is now complete and all the O17 NMR data is presented. The OOF group was also transferred to carbon in that at least two OOF compounds are prepared by the reaction of either O2F2 or O4F2 with perfluoropropylene.
Distribution Classification
1
Distribution Conflict
No
DTIC Record Exists
Yes
Illinois Tech Related
Yes
Report Availability
Not available via Contrails
Type
report
Item sets
Illinois Tech Related